The U.S. Army announced that it would step up its development of fast-acting spray technology for chemical weapons decontamination.
The U.S. Army Combat Capabilities Development Command (CCDC) Chemical Biological Center chemist Joseph Myers has developed a new sprayable decontaminant slurry, the paint-like substance that can decontaminate an entire vehicle quicker and more thoroughly than the previous method of washing it down with soapy water.
Gregory Peterson, Joseph Myers, George Wagner, Matthew Shue, John Davies, Jr., and Joseph Rossin were listed as the inventors on U.S. Patent 10,245,456, “Process for Decontamination and Detoxification with Zirconium Hydroxide-Based Slurry.”
The slurry works by employing a blend of hydrolytic and oxidative chemistries with a small amount of water, solvent, and binder. Because the active ingredients react readily with both blister and nerve agents, it can detoxify a range of chemical warfare agents. In small-scale laboratory studies, Myers has put the slurry to test on the blister agent HD, commonly known as mustard gas, as well as nerve agents GD, or “soman”, and VX.
Following successful lab trials on two-inch panels against multiple chemical agents between 2014 and 2018, Myers graduated his research to large chamber testing.
“This was the first large-scale study for the slurry with neat, or undiluted, chemical warfare agent,” Myers said. “As technologies develop, they need to be proven out on a larger scale.”
Upon receiving additional funding from the Defense Threat Reduction Agency (DTRA), Myers began designing an appropriate large-scale test item for use in the center’s Engineering Directorate Toxic Chamber facility.
“Just because we are testing in a large-scale chamber, doesn’t mean we requisitioned a Humvee and sprayed agent all over it,” Myers said. “Although the facility has the ability to accommodate that kind of work, whatever item we test with has to be disposed of in accordance with local, state, and/or federal regulations as hazardous waste. The test article needs to mimic the attributes of a full scale vehicle, while being a manageable size for waste disposal.”
Instead of a full-sized vehicle, Myers designed an 18 in. X 24 in. mini vehicle door with a window, door handle, seams, screws and threads – all of the things one would expect to find in a typical vehicle door. Testing the slurry on a realistic scenario has to continue to advance the technology readiness level (TRL). Decon slurry currently sits at TRL 5 where researchers must demonstrate the project at an operationally relevant scale. Each readiness level thereafter moves the project closer to field testing. In the end, if everything goes well, decon slurry could be included in a program of record for the Army.
During large-scale testing, operators contaminated doors with HD and contaminated other doors with VX. Doors were decontaminated using the typical method of soapy water and with Myers’ decon slurry.
“For HD, after using the slurry, we could not find any contaminant at all, and a significant amount was applied initially,” Myers said. “With VX, we had one spot of residual agent, and that was a screw thread so it was a place where the slurry simply could not access, which is typical.”
Compared to the soapy water wash down, the slurry performed well.
“It was multiple orders of magnitude better efficacy and better removal using the slurry,” Myers said.
With that outcome, Myers and fellow chemist Janlyn Eikenberg found themselves on a plane to Hawaii the following March to demonstrate the slurry and brief the U.S. Army Pacific Command on the slurry’s development and use.
With the help of private sector company FLIR, who partnered with Myers, the two provided a demonstration of a process called “tactical decontamination.” Tactical decontamination refers to a rapid process in which warfighters use an indicator to locate contamination on their vehicle and a decontaminant to mitigate the contamination.
“The other technology integrated into our demo is called CIDAS – Contaminant Indicator Decontamination Assurance Spray,” Myers said. “CIDAS is an indicator technology. If you spray it on a surface, it will change color in the presence of agent.”
Using a simulant, the FLIR presenter marked the door Myers designed with a large X. She then sprayed the door with CIDAS, which indicated the presence of a contaminant by turning red.
“We then sprayed the door with the slurry. There is a waiting time associated with the slurry. You need time for it to react. We then rinsed off the slurry and applied the CIDAS again. This time, the indicator did not change to red, indicating decontamination was successful,” Myers said.
With success in Hawaii, Myers and Eikenberg demonstrated the slurry’s capability in June, in Germany, once at Ramstein Air Base to the US Air Forces Europe and another in Grafenwoehr to the US Army European Command Chemical Biological Radiological Nuclear Explosive Detachment.
The whole idea behind tactical decontamination is that Soldiers could decontaminate a vehicle quickly and get back in the fight and that goes toward Army readiness,” Myers said. “Without the slurry, you’re basically out of commission until a decontamination unit arrives to do a soapy water wash. The point is to get warfighters and their equipment back in the field as fast as possible, and the slurry does that.”
Currently, those decontamination units rely on hundreds of gallons of water – something that can be hard to find in some environments or have at the ready. Containing 10 percent water, the slurry eliminates that need.
Not just the commands were impressed by the slurry’s performance. DTRA is also enthusiastic about Myers’ product. They have committed to providing funding for the design of a custom and battle- hardened sprayer for the slurry. Up to now, the slurry has been demonstrated with a commercial-off-the-shelf paint sprayer.
Even more good news has come from Myers’ demonstrations. Another private sector company will soon enter into a cooperative research and development agreement with the Center to openly share information in an effort to refine the formula and advance the slurry so that it can be in the hands of warfighters in the next three to five years.